Synthesis of photochromic oligophenylenimines: optical and computational studies.

نویسندگان

  • Armando I Martínez Pérez
  • Oscar Coreño Alonso
  • Julián Cruz Borbolla
  • José M Vásquez-Pérez
  • Juan Coreño Alonso
  • Karina Alemán Ayala
  • Gabriel Luna-Bárcenas
  • Thangarasu Pandiyan
  • Rosa A Vázquez García
چکیده

Phenyleneimine oligomers 4,4'-(((1E,1'E)-(((1E,1'E)-(1,4-phenylenebis-(azanylylidene))bis(methanylylidene))bis(2,5-bis(octyloxy)-4,1-phenylene))bis(methanylyl-idene))-bis(azanylylidene))dianiline (OIC1MS) and 7,7'-(((1E,1'E)-(((1E,1'E)-((9H-fluorene-2,7-diyl)bis(azanylylidene))bis(methanylylidene))bis(2,5-bis(octyloxy)-4,1phenylene))bis- (methanylylidene))bis(azanylylidene))bis(9H-fluoren-2-amine) (OIC2MS) were prepared by means of conventional and mechanochemical synthesis and characterized by FT-IR, 1H- and 13C-NMR techniques. The optical properties of the compounds were studied in solution by using UV-visible spectroscopy, and the optical effects were analyzed as a function of solvent. The results show that OIC2MS exhibits interesting photochromic properties. Furthermore, the structural and electronic properties of the compounds were analyzed by TD-DFT. It was found that the mechanosynthesis is an efficient method for the synthesis of both tetraimines.

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عنوان ژورنال:
  • Molecules

دوره 20 4  شماره 

صفحات  -

تاریخ انتشار 2015